2022 Vol. 2, No. 1

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Perspective
The direct use of enzymatic biofuel cells as functional bioelectronics
Xiao Xinxin
2022, 2(1): 1-9. doi: 10.1016/j.esci.2021.12.005
Abstract(100) HTML (45)
Abstract:
Enzymatic biofuel cells (EBFCs) are a subgroup of fuel cells that use enzymes as catalysts. EBFCs that utilize physiological substrates such as glucose or lactate are of great interest as implantable or wearable power sources to activate medical devices. This contribution introduces the working prin...
Review
Advanced characterizations and measurements for sodium-ion batteries with NASICON-type cathode materials
Liu Yukun, Li Jie, Shen Qiuyu, Zhang Jian, He Pingge, Qu Xuanhui, Liu Yongchang
2022, 2(1): 10-31. doi: 10.1016/j.esci.2021.12.008
Abstract(219) HTML (103)
Abstract:
NASICON (Na superionic conductor)-type cathode materials for sodium-ion batteries (SIBs) have attracted extensive attention due to their mechanically robust three-dimensional (3D) framework, which has sufficient open channels for fast Na+ transportation. However, they usually suffer from inferior el...
Emerging design principles, materials, and applications for moisture-enabled electric generation
Sun Zhaoyang, Wen Xian, Wang Liming, Ji Dongxiao, Qin Xiaohong, Yu Jianyong, Ramakrishna Seeram
2022, 2(1): 32-46. doi: 10.1016/j.esci.2021.12.009
Abstract(326) HTML (139)
Abstract:
Smart generators that collect energy from the ambient environment are a new approach for meeting growing global energy needs. Moisture is one of the most abundant resources in the ambient environment, and using it to generate electricity has aroused great interest in recent years. In this review, we...
Controlling Li deposition below the interface
Cao Wenzhuo, Li Quan, Yu Xiqian, Li Hong
2022, 2(1): 47-78. doi: 10.1016/j.esci.2022.02.002
Abstract(156) HTML (62)
Abstract:
The desire for high-energy-density batteries calls for the revival of the Li metal anode. However, its application is hindered by enormous challenges associated with Li deposition/desolvation behaviors, such as side reactions, volume change, and dendrite formation. To overcome these challenges, Li d...
Research Paper
Li-rich channels as the material gene for facile lithium diffusion in halide solid electrolytes
Yang Guohao, Liang Xianhui, Zheng Shisheng, Chen Haibiao, Zhang Wentao, Li Shunning, Pan Feng
2022, 2(1): 79-86. doi: 10.1016/j.esci.2022.01.001
Abstract(343) HTML (142)
Abstract:
Halide solid electrolytes have attracted intense research interest recently for application in all-solid-state lithium-ion batteries. Herein, we present a systematic first-principles study of the Li3MX6 (M: multivalent cation; X: halogen anion) halide family that unveils the link between Li-rich cha...
Methanol electro-oxidation to formate on iron-substituted lanthanum cobaltite perovskite oxides
Meng Fanxu, Dai Chencheng, Liu Zheng, Luo Songzhu, Ge Jingjie, Duan Yan, Chen Gao, Wei Chao, Chen Riccardo Ruixi, Wang Jiarui, Mandler Daniel, Xu Zhichuan J.
2022, 2(1): 87-94. doi: 10.1016/j.esci.2022.02.001
Abstract(210) HTML (73)
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Electrochemically producing formate by oxidizing methanol is a promising way to add value to methanol. Noble metal-based electrocatalysts, which have been extensively studied for the methanol oxidation reaction, can catalyze the complete oxidation of methanol to carbon dioxide, but not the mild oxid...
Advanced cathode for dual-ion batteries: Waste-to-wealth reuse of spent graphite from lithium-ion batteries
Yang Jia-Lin, Zhao Xin-Xin, Li Wen-Hao, Liang Hao-Jie, Gu Zhen-Yi, Liu Yan, Du Miao, Wu Xing-Long
2022, 2(1): 95-101. doi: 10.1016/j.esci.2021.11.001
Abstract(141) HTML (55)
Abstract:
The amount of spent lithium-ion batteries (LIBs) is constantly increasing as their popularity grows. It is important to develop a recycling method that cannot only convert large amounts of waste anode graphite into high value-added products but is also simple and environmentally friendly. In this wo...
Platinum single-atom catalyst with self-adjustable valence state for large-current-density acidic water oxidation
Su Hui, Soldatov Mikhail A., Roldugin Victor, Liu Qinghua
2022, 2(1): 102-109. doi: 10.1016/j.esci.2021.12.007
Abstract(183) HTML (86)
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The design of active acidic oxygen evolution reaction (OER) catalysts is of paramount importance to achieve efficient large-current-density industrial hydrogen fuel production via water electrolysis. Herein, we develop a Pt-based catalyst with high electrochemical activity for the OER in acidic cond...
Effect of electrolyte anions on the cycle life of a polymer electrode in aqueous batteries
Zhang Ye, Zhao Lihong, Liang Yanliang, Wang Xiaojun, Yao Yan
2022, 2(1): 110-115. doi: 10.1016/j.esci.2022.01.002
Abstract(193) HTML (70)
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Redox polymers are a class of high-capacity, low-cost electrode materials for electrochemical energy storage, but the mechanisms governing their cycling stability are not well understood. Here we investigate the effect of anions on the longevity of a p-dopable polymer through comparing two aqueous z...
Crack-free single-crystalline Co-free Ni-rich LiNi0.95Mn0.05O2 layered cathode
Ni Lianshan, Guo Ruiting, Fang Susu, Chen Jun, Gao Jinqiang, Mei Yu, Zhang Shu, Deng Wentao, Zou Guoqiang, Hou Hongshuai, Ji Xiaobo
2022, 2(1): 116-124. doi: 10.1016/j.esci.2022.02.006
Abstract(171) HTML (60)
Abstract:
The rapid growth in global electric vehicles (EVs) sales has promoted the development of Co-free, Ni-rich layered cathodes for state-of-the-art high energy-density, inexpensive lithium-ion batteries (LIBs). However, progress in their commercial use has been seriously hampered by exasperating perform...